Cluster Of Atoms



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Clusters of twenty gold atoms take on a pyralidal shape. That is what KU Leuven researchers have found using a scanning tunneling microscope.

Freestanding clusters of twenty gold atoms take the shape of a pyramid, researchers discovered. This is in contrast with most elements, which organize themselves by forming shells around one central atom. The team of researchers led by KU Leuven published their findings in Science Advances.

Clusters composed of a few atoms tend to be spherical. They are usually organized in shells of atoms around a central atom. This is the case for many elements, but not for gold! Experiments and advanced computations have shown that freestanding clusters of 20 gold atoms take on a pyramidal shape. They have a triangular ground plane made up of 10 neatly arranged atoms, with additional triangles of 6 and 3 atoms, topped by a single atom (see the figure below, in which a model of twintig oranges is compared with the theoretical and experimental structure).

Researchers used intense plasmas in a complex vacuum chamber setup to sputter gold atoms from a macroscopic piece of gold. 'Part of the sputtered atoms grow together to small particles of a few up to a few tens of atoms, due to a process comparable with condensation of water molecules to droplets,' says Zhe Li, the main author of the paper and currently at the Harbin Institute of Technology. 'We selected a beam of clusters consisting of exactly twenty gold atoms. We landed these species with one of the triangular facets onto a substrate covered with a very thin layer of kitchen salt (NaCl), precisely three atom layers thick.'

The study also revealed the peculiar electronic structure of the small triangular pyramid of gold. Very similar to the noble gas atoms or aromatic molecules, it only has completely filled electron orbitals, which makes them much less reactive than clusters sizes with one or a few atoms more or less.

Gold clusters in the size range of a few to some tens of atoms are known to possess remarkable properties. The reported detailed information on these small gold clusters are important to evaluate their catalytic and optical performances, which is highly relevant for designing cluster-based catalyst and optical devices. Recent applications of clusters include utilization in fuel cells and carbon capture.

  1. Clue: Cluster of atoms (abbr.) We have 1 answer for the clue Cluster of atoms (abbr.).See the results below. Possible Answers: MOL; Related Clues: Tiny particle: Abbr.
  2. Clusters are aggregates of atoms, molecules, or ions that adhere together under forces like those that bind the atoms, ions, or molecules of bulk matter; because of the manner in which they are prepared, clusters remain as tiny particles at least during the course of an experiment.
  3. Cluster of atoms (Abbr.) - crossword puzzle clue Clue: Cluster of atoms (Abbr.) Cluster of atoms (Abbr.) is a crossword puzzle clue that we have spotted 1 time. There are related clues (shown below).
  4. Cluster of atoms (Abbr.) is a crossword puzzle clue. Clue: Cluster of atoms (Abbr.) Cluster of atoms (Abbr.) is a crossword puzzle clue that we have spotted 1 time. There are related clues (shown below).

The study 'Unraveling the atomic structure, ripening behavior, and electronic structure of supported Au20 clusters' was published in the journal ’Science Advances’.

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  • Atom cluster

    Clusters are aggregates of atoms (or molecules) containing between three and a few thousand atoms that have properties intermediate between those of the isolated monomer (atom or molecule) and the bulk or solid-state material. The study of such species has been an increasingly active research field since about 1980. This activity is due to the fundamental interest in studying a completely new area that can bridge the gap between atomic and solid-state physics and also shows many analogies to nuclear physics. However, the research is also done for its potential technological interest in areas such as catalysis, photography, and epitaxy. A characteristic of clusters which is responsible for many of their interesting properties is the large number of atoms at the surface compared to those in the cluster interior. For many kinds of atomic clusters, all atoms are at the surface for sizes of up to 12 atoms. As the clusters grow further in size, the relative number of atoms at the surface scales as approximately 4N-1/3, where N is the total number of atoms. Even in a cluster as big as 105 atoms, almost 10% of the atoms are at the surface. Clusters can be placed in the following categories:

    1. Microclusters have from 3 to 10–13 atoms. Concepts and methods of molecular physics are applicable.

    2. Small clusters have from 10–13 to about 100 atoms. Many different geometrical isomers exist for a given cluster size with almost the same energies. Molecular concepts lose their applicability.

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    3. Large clusters have from 100 to 1000 atoms. A gradual transition is observed to the properties of the solid state.

    4. Small particles or nanocrystals have at least 1000 atoms. These bodies display some of the properties of the solid state.

    The most favored geometry for rare-gas (neon, argon, and krypton) clusters of up to a few thousand atoms is icosahedral. However, the preferred cluster geometry depends critically on the bonding between the monomers in the clusters. For example, ionic clusters such as those of sodium chloride [(NaCl)N] very rapidly assume the cubic form of the bulk crystal lattice, and for metallic clusters it is the electronic structure rather than the geometric structure which is most important. SeeCrystal structure

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    There are two main types of sources for producing free cluster beams. In a gas-aggregation source, the atoms or molecules are vaporized into a cold, flowing rare-gas atmosphere. In a jet-expansion source, a gas is expanded under high pressure through a small hole into a vacuum.

    In most situations, the valence electrons of the atoms making up the clusters can be regarded as being delocalized, that is, not attached to any particular atom but with a certain probability of being found anywhere within the cluster. The simplest and most widely used model to describe the delocalized electrons in metallic clusters is that of a free-electron gas, known as the jellium model. The positive charge is regarded as being smeared out over the entire volume of the cluster, while the valence electrons are free to move within this homogeneously distributed, positively charged background.

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    McGraw-Hill Concise Encyclopedia of Physics. © 2002 by The McGraw-Hill Companies, Inc.